Most of the filesystems ufs, reiser, ext2, ext3, and ext4 (there may be others) have a reserve of a given percentage of disk to be use exclusively by the root userid. This is basically a safety valve allowing the root users or root processes to continue to use disk when things get close on disk while denying the supposedly less important non-root users.
On ext2, and ext3, I believe that the default reservation is 5%, much too high with the sizes of partitions these days. What I usually do is this to my ext filesystems:
tune2fs -m 1 /dev/sda3
This is generally safe to change while the disk is mounted. However, you might have to remount the disk to make it effective immediately.